I did for a few years. Eventually I had to switch to VSCode because any given Jetbrains product is only good at a single language, and constantly switching Jetbrains products is a nightmare. Now that I’ve been using VSCode for a while, there are some extension that are so critical to my workflow Jetbrains is virtually useless to me without them.
Most extensions have good equivalents. Other languages like Julia are VSCode only. Fortran was the language that really made me jump ship, PyCharm’s Fortran extension is barely syntax highlighting. Remote - SSH is the killer though, it is a beautifully made and essential tool for working with remote systems.
Most importantly, PyCharm doesn’t really have any killer features or extensions that makes it essential.